Piedfort means double the standard thickness. These coins were produced only like this, so it's not Piedfort. Just higher thickness. And these are both made from tombac (copper & zink) and silver plated.
Page for these coin are: N#264534
N#356062
Thanks for your weight measurment. That's strange. I measured my piece and it's strange too: 32.77 gram, much more than on attached certificate. It seems that they prepared the coa as for standard coins not the actual ones.

Normal crowns from copper-nickel are 38.6mm and weight 28.28 gram.
Here is the specification that is also allowed for 1 crown coins as per Gibraltar law and it looks this is the case:
One Crown 38.61mm diameter
Tombac Cu85Zn15
Std weight 32.600g with tolerance +/- 0.652g
In coming days, I will update the Numista coin pages for this series to have the correct weight, not the one from certificate.
Edit: Numista pages updated.